Geminate and nongeminate recombination of triplet excitons formed by singlet fission.
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Abstract |
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We report the simultaneous observation of geminate and nongeminate triplet-triplet annihilation in a solution-processable small molecule TIPS-tetracene undergoing singlet exciton fission. Using optically detected magnetic resonance, we identify recombination of triplet pairs directly following singlet fission, as well as recombination of triplet excitons undergoing bimolecular triplet-triplet annihilation. We show that the two processes give rise to distinct magnetic resonance spectra, and estimate the interaction between geminate triplet excitons to be 60 neV. |
Year of Publication |
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2014
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Journal |
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Physical review letters
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Volume |
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112
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Issue |
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23
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Number of Pages |
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238701
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Date Published |
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2014
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ISSN Number |
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0031-9007
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URL |
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https://link.aps.org/abstract/PRL/v112/p238701
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DOI |
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10.1103/PhysRevLett.112.238701
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Short Title |
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Phys Rev Lett
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